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SAFEGUARDING THE
OZONE LAYER AND
THE GLOBAL
CLIMATE SYSTEM
Issues Related to Hydrofluorocarbons
and Perfluorocarbons
Summary for Policymakers and Technical Summary
Intergovernmental Panel on Climate Change
Technology and Economic Assessment Panel
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IPCC/TEAP Special Report on
Safeguarding the Ozone Layer and the Global
Climate System:
Issues Related to Hydro uorocarbons and
Per uorocarbons
Summary for Policymakers
A Report of Working Groups I and III of the IPCC
and
Technical Summary
A Report accepted by Working Groups I and III of the IPCC but not approved
in detail
This report was produced by the Intergovernmental Panel on Climate Change (IPCC) and the
Technology and Economic Assessment Panel (TEAP) on the invitation of the United Nations
Framework Convention on Climate Change and the Montreal Protocol
ISBN 92-9169-118-6
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Foreword
e Intergovernmental Panel on Climate Change (IPCC) was
jointly established by the World Meteorological Organization
(WMO) and the United Nations Environment Programme
(UNEP) in 1988 to assess available information on the science,
the impacts, and the economics of, and the options for mitigating
and/or adapting to, climate change. In addition, the IPCC
provides, on request, scientifi c, technical, and socio-economic
advice to the Conference of the Parties (COP) to the United
Nations Framework Convention on Climate Change (UNFCCC).
e IPCC has produced a series of Assessment Reports, Special
Reports, Technical Papers, methodologies, and other products
that have become standard works of reference and that are widely
used by policymakers, scientists, and other experts.
After the decision of the Eighth Conference of the Parties to
the UNFCCC 1 , the Fourteenth Meeting of the Parties to
the Montreal Protocol (Rome, Italy, 25-29 November 2002),
welcomed this decision, and requested the TEAP to work with the
IPCC in preparing the Special Report, and requested simultaneous
submission of the report to the Open Ended Working Group
under e Montreal Protocol and the UNFCCC SBSTA. e
scope, structure, and outline of the Special Report were approved
by the IPCC in plenary meetings during its Twentieth Session in
Paris, France, from 19-21 February 2003.
As is usual in the IPCC, success in producing this report has
depended fi rst and foremost on the enthusiasm and cooperation
of experts worldwide in many related but diff erent disciplines. We
would like to express our gratitude to all the Coordinating Lead
Authors, Lead Authors, Contributing Authors, Review Editors,
and Expert Reviewers. ese individuals have devoted enormous
time and eff ort to produce this report and we are extremely grateful
for their commitment to the IPCC process.
e Special Report on Safeguarding the Ozone Layer and the Global
Climate System was developed in response to invitations by the United
Nations Framework Convention on Climate Change (UNFCCC) 1
and the Montreal Protocol on Substances that Deplete the Ozone
Layer 2 . IPCC and the Montreal Protocol’s Technology and Economic
Assessment Panel (TEAP) were asked to work together to develop
a balanced scientifi c, technical and policy-relevant Special Report.
e request covered both a scientifi c assessment of the interrelations
between the ozone layer and climate change and development of
user-friendly and policy-neutral information to assist all Parties
and stakeholders in making informed decisions when evaluating
alternatives to ozone-depleting substances.
We would also like to express our sincere thanks to the Steering
Committee for this Report, which consisted of co-chairs from
both the Technology and Economic Assessment Panel (TEAP)
and the Intergovernmental Panel on Climate Change (IPCC):
Stephen Andersen, Lambert Kuijpers, and José Pons
for the Technology and Economic Assessment Panel (TEAP),
and
Discussions on these topics have a long history, including
deliberations at the Fourth Conference of the Parties to the
UNFCCC (held in 1998 in Buenos Aires) which invited
Parties and all other relevant entities to provide information to
the UNFCCC Secretariat on available and potential ways and
means of limiting emissions of hydrofl uorocarbons (HFCs) and
perfl uorocarbons (PFCs) when used as replacements for ozone
depleting substances. In 1999, an IPCC/TEAP Expert Meeting
was organized 3 , which addressed the issue and forms important
background for the present eff ort, along with new information on
science, technology, and policy needs.
Susan Solomon, Ogunlade Davidson and Bert Metz (chair of
the Steering Committee)
for the Intergovernmental Panel on Climate Change (IPCC).
We are convinced that this Special Report provides a balanced
scientifi c, technical and policy-related assessment that will assist
all concerned in taking decisions when considering alternatives to
ozone-depleting substances.
Michel Jarraud
Secretary-General,
World Meteorological Organization
Klaus Töpfer
Executive Director,
United Nations Environment Programme and
Director-General,
United Nations O ce in Nairobi
1 Decision 12/CP.8, FCCC/CP/2002/7/Add.1, page 30. Eight Conference of the Parties to the UNFCCC, New Delhi, India, 23 October – 1 November 2002
2 Decision XIV/10 UNEP/OzL.Pro.14/9, page 42. Fourteenth Meeting of the Parties to the Montreal Protocol, Rome, Italy, 25-29 November 2002
3 Proceedings of the Joint IPCC/TEAP Expert Meeting on options for the limitation of emissions of HFCs and PFCs, Petten, e Netherlands, 26-28 May 1999, see
http://www.ipcc-wg3.org/docs/IPCC-TEAP99/index.html
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Preface
is Special Report on Safeguarding the Ozone and the Global Climate
System has been developed in response to invitations from Parties to
the UNFCCC and the Montreal Protocol. It provides information
relevant to decision-making in regard to safeguarding the ozone
layer and the global climate system: two global environmental
issues involving complex scientifi c and technical considerations.
e scope, structure, and outline of this Special Report were
approved by the IPCC at its Twentieth Session in Paris, France,
19–21 February 2003. e responsibility for preparing the report
was given jointly to IPCC’s Working Groups I and III and the
Montreal Protocol's Technology and Economic Assessment Panel
(TEAP). A joint IPCC/ TEAP Steering Committee (see below)
was established to manage preparation of the report following
IPCC procedures.
decisions under the Montreal Protocol Multilateral Fund. When
the Kyoto Protocol was negotiated in 1997, countries had new
incentives to take account of how choices among substitutes
could aff ect the objectives of both protocols. ese considerations
created a need for more comprehensive information regarding
options for ODS replacement that take into account the need of
safeguarding the ozone layer as well as the global climate system.
In May 1999, the IPCC and TEAP held a joint expert meeting on
options for the limitation of Emissions of HFCs and PFCs and
in October 1999 TEAP published its report: “ e implications
to the Montreal Protocol of the Inclusion of HFCs and PFCs
in the Kyoto Protocol”. is Special Report of 2005 is the latest
cooperative eff ort.
e potential of each ODS substitute to infl uence the climate
system depends not only upon the physical and chemical properties
of the substance itself but also upon the factors that infl uence
emissions to the atmosphere, such as containment, recycling,
destruction and energy e ciency in particular applications. Gases,
applications and sectors considered in the report are those related
to emissions of CFCs, HCFCs, HFCs and PFCs, as well as to
alternatives for the use of HFCs and PFCs. e report does not
consider unrelated industrial or other uses of the same chemicals
e report covers chemicals and technologies in use or likely to be
used in the next decade.
Background
Scientifi c evidence linking chlorofl uorocarbons (CFCs) and other
Ozone Depleting Substances (ODSs) to global ozone depletion
led to the initial control of chemicals under the 1987 Montreal
Protocol and to Amendments and Adjustments in the 1990s
that added additional ODSs, agreed phaseouts, and accelerated
those phaseouts. is international process has resulted in (i)
elimination of production of most CFCs, methyl chloroform, and
halons, (ii) the increased use of existing hydrochlorofl uorocarbons
(HCFCs), (iii) the new production of a wide range of industrial
fl uorine containing chemicals, including new types of HCFCs,
hydrofl uorocarbons (HFCs) and perfl uorocarbons (PFCs), (iv)
use of non-halogenated chemical substitutes such as hydrocarbons,
carbon dioxide and ammonia and (v) the development of not-
in-kind alternative methods such as water-based cleaning
procedures.
Organization of the Report
e report provides the scientifi c context required for consideration
of choices among alternatives to ODSs (chapters 1 and 2); potential
methodologies for assessing options (chapter 3); and technical
issues relating to GHG emission reduction opportunities for each
of the sectors involved, including refrigeration, air conditioning,
foams, aerosols, fi re protection and solvents (chapters 4 to 10).
e report also addresses the future availability of HFCs (chapter
11).
e likelihood that CFCs and other ODSs also aff ect the climate
system was fi rst identifi ed in the 1970s, and the global warming
eff ectiveness of halocarbons, including HFCs, has been further
elucidated over the past three decades. For example, the 1989
Scientifi c Assessment of Stratospheric Ozone included a chapter
on halocarbon global warming potentials (GWPs) and the 1989
Technology Assessment presented these GWPs in discussions of the
importance of energy e ciency in insulating foam, refrigeration,
and air conditioning. As various approaches were developed to the
phase-out of ODSs under the Montreal Protocol, it was realized
that some actions taken to reduce future depletion of the ozone
layer, in particular the introduction of HFCs and PFCs, could
increase or decrease global warming impact.
Chapters 1 and 2 address linkages between ozone depletion and
climate change, and draw from previous international scientifi c
assessments, particularly the periodic assessments conducted under
the auspices of WMO, UNEP, and the IPCC (e.g., the most recent
Scientifi c Assessment of Ozone Depletion, 2002 , the Assessment of
the Environmental Impacts of Ozone Depletion, 2002 , and Climate
Change: e Scientifi c Basis, 2001 ). Chapter 1 covers stratospheric
chemistry and dynamics and their coupling to climate change,
while chapter 2 covers radiative forcing of each of the relevant gases
as well as their roles in tropospheric chemistry and air quality. e
present report does not seek to cover the breadth and depth of the
more specialized ozone and climate change assessments, but rather
to provide a summary of relevant interactions between the two
is scientifi c and technical information allowed Parties to the
Montreal Protocol to choose options to replace ODSs, mindful of
the global warming impact and was refl ected in some investment
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iv
environmental issues to aid the understanding and application of
the rest of the report.
e fi nal report was considered by a joint Session of IPCC
Working Groups I and III held in Addis Ababa from April 6 th
to 8 th , 2005, where the SPM was approved line-by-line and the
underlying report was accepted by the IPCC Panel.
Chapter 3 summarizes available methodologies to characterize or
compare technologies (such as the lifecycle climate performance
parameter, LCCP), particularly those approaches that are applied
across the diverse sectors covered in this report.
Acknowledgements
e Steering Committee sincerely appreciates all the Coordinating
Lead Authors, Lead Authors, and Review Editors whose expertise,
diligence, and patience have underpinned the successful
completion of this report and who generously contributed
substantial amounts of their professional and personal time, and
the contribution of the many contributors and reviewers for their
valuable and painstaking dedication and work.
Chapters 4 through 10 then provide technical descriptions
and information for each of the key sectors of halocarbon use:
refrigeration (4), residential and commercial air conditioning
and heating (5), mobile air conditioning (6), foams (7), medical
aerosols (8), fi re protection (9), and non-medical aerosols, solvents
and HFC-23 byproduct emissions from HCFC-22 production
(10). Each chapter provides an overview of its sector, the relevant
technologies, information on consumption and emission of
relevant gases, and practices and alternative technologies to reduce
emissions and net warming impacts. is includes consideration
of process improvement in applications, improved containment,
recovery and recycling during operation, end-of-life recovery,
disposal and destruction. e choices among options within each
sector involve detailed consideration of technical factors including
performance, environmental health and safety, cost, availability of
alternatives, and total energy and resource e ciencies.
Chapter 11 covers both supply and demand issues for HFCs,
and integrates emissions estimates across sectors and regions. It
aggregates the emissions information for various chemicals from
the various sectors, and considers the balance between supply and
demand of HFCs.
We also thank Marco Gonzalez and Megumi Seki from UNEP’s
Ozone Secretariat, for their co-sponshorship, fi nancial support
and commitment to the process that led to this report.
We thank the Governments of the Netherlands, United States of
America, Japan, and Argentina for hosting the four report drafting
meetings, and the Government of Ethiopia and the United Nations
Centre in Addis Ababa for hosting the Joint Working Group I and
III Session.
We also thank Renate Christ, Secretary of the IPCC, and the
staff of the IPCC Secretariat, who provided logistical support for
government liaison and travel of experts from the developing and
transitional economy countries.
Finally we also thank the staff of the Working Groups I and III
Technical Support Units, for their work in preparing the report,
in particular David de Jager (Secretary of the Steering Committee,
TSU WG III), Martin Manning (Head TSU WG I), Leo Meyer
(Head TSU WG III) for their scientifi c and management support,
and Tahl Kestin, Scott Longmore, Melinda Tignor (WGI), Heleen
de Coninck, Anita Meier, Martin Middelburg, Rob Puijk, and
elma van den Brink (WG III) for their technical and logistic
support. Special thanks to Christine Ennis, Dave omas and
Pete omas for their contribution to the copy-editing of the fi nal
draft of this report.
As in past IPCC reports, this report contains a Summary for
Policymakers (SPM) and a Technical Summary (TS), in addition
to the main chapters. Each section of the SPM and TS has been
referenced to the appropriate section of the relevant chapter, so
that material in the SPM and TS can easily be followed up in
further detail in the chapters. e report also contains annexes
with a the list of Authors and Expert Reviewers, a glossary, a list of
acronyms and abbreviations, a list of units and conversion factors,
and an overview of major chemical formulae and nomenclature of
substances that are considered in this report.
e report was compiled between August 2003 and April 2005
by 145 experts from 35 countries. e draft report was circulated
for review by experts, which submitted valuable suggestions for
improvement. is was followed by a second review by both
governments and experts. In these two review rounds, about 6600
comments were received from about 175 experts, governments
and non-governmental organizations. is review process, and
its oversight by Review Editors who are independent of the
author teams, is an intrinsic part of any IPCC assessment and is
an important part of ensuring the quality and credibility of the
product.
e Steering Committee for this Report:
Stephen O. Andersen, Co-Chair of the TEAP
Ogunlade Davidson, Co-Chair of IPCC Working Group III
Lambert Kuijpers, Co-Chair of the TEAP
Bert Metz, Co-Chair of IPCC Working Group III (Chair of
the Steering Committee)
José Pons, Co-Chair of the TEAP
Susan Solomon, Co-Chair of IPCC Working Group I
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